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Pharmacologically speaking, codeine, one of the phenanthrene alkaloids of opium that is naturally present in the opium poppy, is classified as a narcotic analgesic. Phenol 7,8-Didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan-6α-ol/1:1)(Acid) Codeine phosphate is known by its chemical name, hemihydrate.